Safety Department AKEMI chemisch technische Spezialfabrik GmbH

Declaraciones de peligro (CLP)

H226, H302, H312, H314, H315, H317, H318, H319, H331, H332, H361d, H373, H411, H412

Código

Declaraciones

H226

Flammable liquid and vapour

Pictogramas de peligro

GHS05 GHS07 · Signal word Danger · Hazard-determining components of labelling: 4,4'-Isopropylidenediphenol, oligomeric reaction products with 1-chloro-2,3- epoxypropane, reaction products with m-phenylenebis(methylamine) 3-aminomethyl-3,5,5-trimethylcyclohexylamine 1,3-Benzenedimethanamine, reaction products with glycidyl tolyl ether N-(3-(trimethoxysilyl)propyl)ethylenediamine phenole, styrenated · Hazard statements H314 Causes severe skin burns and eye damage. H317 May cause an allergic skin reaction. H412 Harmful to aquatic life with long lasting effects. (Contd. on page 2) Trade name: Akepox 4050 Anti-Slip Mix Component B (Contd. of page 1) · Precautionary statements P101 If medical advice is needed, have product container or label at hand. P102 Keep out of reach of children. P103 Read carefully and follow all instructions. P260 Do not breathe mist/vapours/spray. P271 Use only outdoors or in a well-ventilated area. P280 Wear protective gloves/protective clothing/eye protection/face protection/hearing protection. P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water [or shower]. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310 Immediately call a POISON CENTER/doctor. P333+P313 If skin irritation or rash occurs: Get medical advice/attention. P405 Store locked up. P501 Dispose of contents/container in accordance with local/ regional/national/international regulations.

Otros peligros

Results of PBT and vPvB assessment

PBT

Not applicable.

MPmB

1760-24-3 N-(3-(trimethoxysilyl)propyl)ethylenediamine * SECTION 3: Composition/information on ingredients · 3.2 Chemical characterisation: Mixtures · Description: Mixture of substances listed below with nonhazardous additions. · Dangerous components: CAS: 100-51-6 Benzyl alcohol <12.5% EINECS: 202-859-9 Acute Tox. 4, H302; Acute Tox. 4, H312; Acute Tox. 4, H332; Eye Irrit. Index number: 603-057-00-5 2, H319 Reg.nr.: 01-2119492630-38-0000 CAS: 113930-69-1 4,4'-Isopropylidenediphenol, oligomeric reaction products with 1-chloro- <10% NLP: 500-302-7 2,3-epoxypropane, reaction products with m-phenylenebis(methylamine) Reg.nr.: 01-2119965162-39 Skin Corr. 1B, H314; Eye Dam. 1, H318 Aquatic Chronic 2, H411 Skin Sens. 1, H317 CAS: 90194-04-0 1,3-Benzenedimethanamine, reaction products with glycidyl tolyl ether 1-5% EINECS: 290-611-0 Eye Dam. 1, H318 Reg.nr.: 01-2120770491-54 Aquatic Chronic 2, H411 Acute Tox. 4, H302; Skin Irrit. 2, H315; Skin Sens. 1, H317 CAS: 2855-13-2 3-aminomethyl-3,5,5-trimethylcyclohexylamine 1-5% EINECS: 220-666-8 Skin Corr. 1B, H314; Eye Dam. 1, H318 Index number: 612-067-00-9 Acute Tox. 4, H302; Acute Tox. 4, H312; Skin Sens. 1A, H317 Reg.nr.: 01-2119514687-32-0000 Aquatic Chronic 3, H412 CAS: 1760-24-3 N-(3-(trimethoxysilyl)propyl)ethylenediamine 1-5% EINECS: 217-164-6 STOT RE 2, H373 Reg.nr.: 01-2119970215-39 Eye Dam. 1, H318 Acute Tox. 4, H332; Skin Sens. 1, H317 (Contd. on page 3) Trade name: Akepox 4050 Anti-Slip Mix Component B (Contd. of page 2) CAS: 61788-44-1 phenole, styrenated 1-5% EINECS: 262-975-0 Aquatic Chronic 2, H411 Reg.nr.: 01-2119979575-18 Skin Irrit. 2, H315; Skin Sens. 1, H317 CAS: 69-72-7 salicylic acid <1% EINECS: 200-712-3 Repr. 2, H361d Index number: 607-732-00-5 Eye Dam. 1, H318 Reg.nr.: 01-2119486984-17 Acute Tox. 4, H302 CAS: 103-83-3 benzyldimethylamine <1% EINECS: 203-149-1 Flam. Liq. 3, H226 Index number: 612-074-00-7 Acute Tox. 3, H331 Reg.nr.: 01-2119529232-48-xxxx Skin Corr. 1B, H314; Eye Dam. 1, H318 Acute Tox. 4, H302; Acute Tox. 4, H312 Aquatic Chronic 3, H412

Información adicional

For the wording of the listed hazard phrases refer to section 16. * SECTION 4: First aid measures · 4.1 Description of first aid measures · General information: Take affected persons out into the fresh air. Position and transport stably in side position. Immediately remove any clothing soiled by the product. · After inhalation: Supply fresh air and to be sure call for a doctor. In case of unconsciousness place patient stably in side position for transportation. · After skin contact: If skin irritation continues, consult a doctor. Immediately wash with water and soap and rinse thoroughly. · After eye contact: Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor. · After swallowing: If symptoms persist consult doctor. · Information for doctor: Nonylphenol based exposition: causes corrosive burns, damages respiratory tract, eyes, skin and digestive system up to complete tissue destruction. Temporary dysfunctions such as dizziness, headache, nausea and diarrhea may occur. Can cause health disturbances like dermal bleaching, renal and hepatic damage. Amines: Inhalation, swallowing or dermal contact may cause health damages. Cause burns, harm respiratory tract, eyes, skin, and digestion system in worst case up to complete destruction. Intermediate interferences such as headache, nausea, cough, dyspnea may occur. May cause allergies. Sensitized users may react towards very low amine concentrations and should avoid any further contact with this group of chemicals. · 4.2 Most important symptoms and effects, both acute and delayed Headache Dizziness Nausea Breathing difficulty Coughing Allergic reactions · Hazards Danger of impaired breathing. · 4.3 Indication of any immediate medical attention and special treatment needed If swallowed, gastric irrigation with added, activated carbon. * SECTION 5: Firefighting measures · 5.1 Extinguishing media · Suitable extinguishing agents: Use fire extinguishing methods suitable to surrounding conditions. (Contd. on page 4) Trade name: Akepox 4050 Anti-Slip Mix Component B (Contd. of page 3) · 5.2 Special hazards arising from the substance or mixture Formation of toxic gases is possible during heating or in case of fire. In case of fire, the following can be released: Carbon monoxide (CO) Nitrogen oxides (NOx) Under certain fire conditions, traces of other toxic gases cannot be excluded. · 5.3 Advice for firefighters · Protective equipment: Wear fully protective suit. Wear self-contained respiratory protective device. Do not inhale explosion gases or combustion gases. Collect contaminated fire fighting water separately. It must not enter the sewage system. Dispose of fire debris and contaminated fire fighting water in accordance with official regulations. * SECTION 6: Accidental release measures · 6.1 Personal precautions, protective equipment and emergency procedures Ensure adequate ventilation Use respiratory protective device against the effects of fumes/dust/aerosol. · 6.2 Environmental precautions: Do not allow to penetrate the ground/soil. Do not allow product to reach sewage system or any water course. Inform respective authorities in case of seepage into water course or sewage system. Do not allow to enter sewers/ surface or ground water. · 6.3 Methods and material for containment and cleaning up: Dispose of the material collected according to regulations. Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). Ensure adequate ventilation. · 6.4 Reference to other sections See Section 7 for information on safe handling. See Section 8 for information on personal protection equipment. See Section 13 for disposal information. * SECTION 7: Handling and storage · 7.1 Precautions for safe handling Keep receptacles tightly sealed. Store in cool, dry place in tightly closed receptacles. Use only in well ventilated areas. Ensure good ventilation/exhaustion at the workplace. · Information about fire - and explosion protection: No special measures required. · 7.2 Conditions for safe storage, including any incompatibilities · Storage: · Requirements to be met by storerooms and receptacles: Store only in the original receptacle. Prevent any seepage into the ground. · Information about storage in one common storage facility: Store away from oxidising agents. Store away from foodstuffs. · Further information about storage conditions: Store receptacle in a well ventilated area. Keep container tightly sealed. · Storage class: 8 A (Contd. on page 5) Trade name: Akepox 4050 Anti-Slip Mix Component B (Contd. of page 4) · 7.3 Specific end use(s) No further relevant information available. * SECTION 8: Exposure controls/personal protection · 8.1 Control parameters · Additional information about design of technical facilities: No further data; see item 7. · Ingredients with limit values that require monitoring at the workplace: The product does not contain any relevant quantities of materials with critical values that have to be monitored at the workplace. · DNELs 100-51-6 Benzyl alcohol Oral DNEL (Kurzzeit-akut) 20 mg/kg bw/day (BEV) DNEL (Langzeit-wiederholt) 4 mg/kg bw/day (BEV) Dermal DNEL (Kurzzeit-akut) 40 mg/kg bw/day (ARB) 20 mg/kg bw/day (BEV) DNEL ( Langzeit-wiederholt) 8 mg/kg bw/day (ARB) 4 mg/kg bw/day (BEV) Inhalative DNEL (Kurzzeit-akut) 110 mg/m³ Air (ARB) 27 mg/m³ Air (BEV) DNEL (Langzeit-wiederholt) 22 mg/m³ Air (ARB) 5.4 mg/m³ Air (BEV) 2855-13-2 3-aminomethyl-3,5,5-trimethylcyclohexylamine Oral DNEL (Langzeit-wiederholt) 0.526 mg/kg bw/day (BEV) Inhalative DNEL (Kurzzeit-akut) 20.1 mg/m³ Air (ARB) DNEL (Langzeit-wiederholt) 0.073 mg/m³ Air (ARB) 1760-24-3 N-(3-(trimethoxysilyl)propyl)ethylenediamine Oral DNEL (Langzeit-wiederholt) 2.5 mg/kg bw/day (BEV) Dermal DNEL (Kurzzeit-akut) 5 mg/kg bw/day (ARB) 17 mg/kg bw/day (BEV) DNEL ( Langzeit-wiederholt) 5 mg/kg bw/day (ARB) 2.5 mg/kg bw/day (BEV) Inhalative DNEL (Langzeit-wiederholt) 35.3 mg/m³ Air (ARB) 8.7 mg/m³ Air (BEV) 69-72-7 salicylic acid Oral DNEL (Kurzzeit-akut) 4 mg/kg bw/day (BEV) DNEL (Langzeit-wiederholt) 1 mg/kg bw/day (BEV) Dermal DNEL ( Langzeit-wiederholt) 2.3 mg/kg bw/day (ARB) 1 mg/kg bw/day (BEV) Inhalative DNEL (Langzeit-wiederholt) 4 mg/m³ Air (ARB) 0.2-4 mg/m³ Air (BEV) 103-83-3 benzyldimethylamine Oral DNEL (Kurzzeit-akut) 0.5 mg/kg bw/day (BEV) DNEL (Langzeit-wiederholt) 0.25 mg/kg bw/day (BEV) Dermal DNEL (Kurzzeit-akut) 2.8 mg/kg bw/day (ARB) 1 mg/kg bw/day (BEV) DNEL ( Langzeit-wiederholt) 1.4 mg/kg bw/day (ARB) (Contd. on page 6) Trade name: Akepox 4050 Anti-Slip Mix Component B (Contd. of page 5) 0.5 mg/kg bw/day (BEV) Inhalative DNEL (Kurzzeit-akut) 9.9 mg/m³ Air (ARB) 1.74 mg/m³ Air (BEV) DNEL (Langzeit-wiederholt) 1-14.6 mg/m³ Air (ARB) 0.87 mg/m³ Air (BEV) · PNECs 100-51-6 Benzyl alcohol PNEC (wässrig) 39 mg/l (KA) 0.1 mg/l (MW) 1 mg/l (SW) 2.3 mg/l (WAS) PNEC (fest) 0.456 mg/kg Trockengew (BO) 0.527 mg/kg Trockengew (MWS) 5.27 mg/kg Trockengew (SWS) 2855-13-2 3-aminomethyl-3,5,5-trimethylcyclohexylamine PNEC (wässrig) 3.18 mg/l (KA) 0.006 mg/l (MW) 0.06 mg/l (SW) 0.23 mg/l (WAS) PNEC (fest) 1.121 mg/kg Trockengew (BO) 0.578 mg/kg Trockengew (MWS) 5.784 mg/kg Trockengew (SWS) 1760-24-3 N-(3-(trimethoxysilyl)propyl)ethylenediamine PNEC (wässrig) 25 mg/l (KA) 0.0062 mg/l (MW) 0.062 mg/l (SW) 0.62 mg/l (WAS) PNEC (fest) 0.0085 mg/kg Trockengew (BO) 0.022 mg/kg Trockengew (MWS) 0.22 mg/kg Trockengew (SWS) 69-72-7 salicylic acid PNEC (wässrig) 162 mg/l (KA) 0.02 mg/l (MW) 0.2 mg/l (SW) PNEC (fest) 0.166 mg/kg Trockengew (BO) 0.142 mg/kg Trockengew (MWS) 1.42 mg/kg Trockengew (SWS) 103-83-3 benzyldimethylamine PNEC (wässrig) 534 mg/l (KA) 0.00048 mg/l (MW) 0.0048 mg/l (SW) PNEC (fest) 0.0114 mg/kg Trockengew (BO) 0.0071 mg/kg Trockengew (MWS) 0.071 mg/kg Trockengew (SWS) The lists valid during the making were used as basis. (Contd. on page 7) Trade name: Akepox 4050 Anti-Slip Mix Component B (Contd. of page 6) · 8.2 Exposure controls · Personal protective equipment: · General protective and hygienic measures: Do not eat, drink, smoke or sniff while working. Use skin protection cream for skin protection. Clean skin thoroughly immediately after handling the product. Keep away from foodstuffs, beverages and feed. Immediately remove all soiled and contaminated clothing Wash hands before breaks and at the end of work. Do not inhale gases / fumes / aerosols. Avoid contact with the eyes and skin. · Respiratory protection: Short term filter device: Filter A/P2 In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use self-contained respiratory protective device. · Protection of hands: Preventive skin protection by use of skin-protecting agents is recommended. After use of gloves apply skin-cleaning agents and skin cosmetics. Skin protection agent recommendation for preventive skin shelter in application and combination of protective gloves: STOKO EMULSION (http://www.stoko.com) Skin protection recommendation for skin cleaning after product handling: Kresto Classic (http://debstoko.com) Skin protection agent recommendation for skin aftercare: STOKO VITAN (http://www.stoko.com) The protection gloves to be used have to comply with the specifications of the directive 89/686/EC and the directive derived decree EN374, respectively, e.g. the above listed protection glove type. The mentioned permeation times´ data were generated and verified with material samples of the recommended protection glove type in the scope of laboratory anylyses of the company KCL GmbH in compliance with EN374. This recommendation refers exclusively to the material safety data sheet referenced product delivered by Akemi and the indicated field of application. In case of product dilution or in case of mixture with different substances or chemicals, and in condition of EN374 deviation the producer of CE-approved protection gloves must be contacted for detailed information (e.g., KCL GmbH, Germany, 36124 Eichenzell, internet: http://www.kcl.de). Protective gloves The glove material has to be impermeable and resistant to the product/ the substance/ the preparation. Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the chemical mixture. Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation · Material of gloves Butyl rubber, BR The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the application. · Penetration time of glove material Value for the permeation: Level  6, 480 min The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be observed. · For the permanent contact gloves made of the following materials are suitable: Butyl rubber, BR Butoject (KCL, Art_No. 897, 898) (Contd. on page 8) Trade name: Akepox 4050 Anti-Slip Mix Component B (Contd. of page 7) Nitrile rubber, NBR Camatril (KCL, Art_No. 730, 731, 732, 733) Dermatril (Art_No. 740, 741, 742) · As protection from splashes gloves made of the following materials are suitable: Butyl rubber, BR Butoject (KCL, Art_No. 897, 898) Nitrile rubber, NBR Camatril (KCL, 730, 731, 732, 733) Chloroprene rubber, CR Camapren (KCL, Art_No. 720, 722, 726) · Not suitable are gloves made of the following materials: Natural rubber, NR Fluorocarbon rubber (Viton) Leather gloves Strong material gloves · Eye protection: Tightly sealed goggles · Body protection: Protective work clothing * SECTION 9: Physical and chemical properties · 9.1 Information on basic physical and chemical properties · General Information · Appearance: Form: Pasty Colour: Dark grey · Odour: Characteristic · pH-value: Not applicable · Change in condition Melting point/freezing point: Undetermined. Initial boiling point and boiling range: >200 °C · Flash point: >100 °C · Ignition temperature: 435 °C · Decomposition temperature: > 200 °C · Auto-ignition temperature: Product is not selfigniting. · Explosive properties: Product does not present an explosion hazard. · Explosion limits: Lower: 1.3 Vol % Upper: 13 Vol % · Vapour pressure at 20 °C: 0.1 hPa · Density at 20 °C: 1.96 g/cm³ · Solubility in / Miscibility with water: Not miscible or difficult to mix. · Viscosity: Dynamic at 20 °C: 85,000 mPas Kinematic: Not determined. · Solvent content: Organic solvents: 12.3 % (Contd. on page 9) Trade name: Akepox 4050 Anti-Slip Mix Component B (Contd. of page 8) Solids content: 75.8 % · 9.2 Other information No further relevant information available. * SECTION 10: Stability and reactivity · 10.1 Reactivity No further relevant information available. · 10.2 Chemical stability · Thermal decomposition / conditions to be avoided: No decomposition if used and stored according to specifications. · 10.3 Possibility of hazardous reactions Strong exothermic reaction with acids. Reacts with strong oxidising agents. · 10.4 Conditions to avoid No further relevant information available. · 10.5 Incompatible materials: No further relevant information available. · 10.6 Hazardous decomposition products: Corrosive gases/vapours * SECTION 11: Toxicological information · 11.1 Information on toxicological effects · Acute toxicity Based on available data, the classification criteria are not met. · LD/LC50 values relevant for classification: ATE (Acute Toxicity Estimates)